Mono- and Binuclear Gold(I) Compounds Containing Deprotonated Purines and Pyrimidines

نویسندگان

  • Flavio Bonati
  • Alfredo Burini
  • Bianca Rosa Pietroni
چکیده

In the presence of alkali and LAuCl one or two —N H — groups of a purine or pyrimidine base can be transformed into -N (AuL)groups giving stable and soluble compounds containing one or two two-coordinated gold(I) nuclei; mononuclear L A u-Q ' or binuclear LA u-Q -A uL with a monodentate Q " or an exobidentate O '" ligand, resp. (Q 'H = adenine, guanine, theobromine, theophylline, azaguanine or cytosine; Q H 2 thymine or uracyl; L = triphenylphosphine).

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تاریخ انتشار 2012